Freebase vs SALT Nicotine?

Freebase Nicotine

Freebase nicotine is the purest and most traditional form of nicotine used in cigarettes and the majority of e-liquids since the early days of vaping. It is created by treating naturally derived nicotine with ammonia to remove protons and convert it into a deprotonated, or "free," base state. This process increases its pH level (alkalinity) and potency, making it more easily vaporized and absorbed by the body than its natural salt form, though at a slower rate than modern nicotine salts. 

Key Characteristics

  • Pronounced Throat Hit: Due to its higher pH level, freebase nicotine provides a more intense, sometimes harsh, throat hit. This sensation becomes more severe at higher nicotine strengths (above 12mg). Many former smokers who desire the tactile sensation of smoking prefer this quality.
  • Slower Absorption: Freebase nicotine is absorbed into the bloodstream more slowly compared to nicotine salts, resulting in a more gradual and prolonged nicotine effect. This means users may need to vape more frequently to satisfy cravings.
  • Lower Nicotine Strengths: Because of the harshness at high concentrations, freebase e-liquids are typically available in lower strengths, such as 0mg, 3mg, 6mg, and 12mg.
  • Large Vapor Production: Freebase nicotine is often used in high-powered, sub-ohm devices (box mods) that produce large, dense clouds of vapor, appealing to "cloud chasers" and hobbyist vapers.
  • Flavor Clarity: The higher pH of freebase nicotine can sometimes affect the e-liquid's flavor profile, though many vapers feel it allows for a cleaner, more robust taste that enhances complex flavors.
  • Cost-Effective: Freebase e-liquids are generally more affordable and widely available than nicotine salts.

Summary of Differences

Features Freebase Nicotine Nicotine Salts
Throat Hit Harsher, pronounced "kick" at higher strengths Smooth, even at high strengths
Absorption Rate Slower absorption Rapid absorption, mimicking cigarettes
Nicotine Strengths Typically lower (0mg - 12mg) Typically higher (20mg - 50mg)
Device Compatibility Best with high-wattage, sub-ohm devices Best with low-wattage pod systems
Vapor Production Large, dense clouds Small, discreet clouds
Chemical Stability Prone to oxidation, shorter shelf life More stable, longer shelf life

Salt Nicotine

Salt nicotine(also known as nic salts or salt nic) is a form of nicotine used in e-liquids that is made by combining freebase nicotine with a mild organic acid, typically benzoic acid. This chemical modification lowers the nicotine's pH level (alkalinity), resulting in a much smoother throat hit even at high nicotine concentrations, and allows for faster absorption into the bloodstream, more closely mimicking the experience of smoking a traditional cigarette

Key Differences from Freebase Nicotine

Features Nicotine Salts Freebase Nicotine
Throat Hit Smooth, minimal hit even at high strengths. Harsher, especially at higher nicotine levels.
Absorption Rate Rapidly absorbed into the bloodstream. Slower absorption into the bloodstream.
Nicotine Strengths Typically available in higher strengths (e.g., 20mg, 50mg). Typically available in lower strengths (e.g., 3mg, 6mg, 12mg).
Device Compatibility Best used in low-wattage devices and pod systems. Best used in high-wattage, sub-ohm devices.
Vapor Production Produces small, discreet clouds of vapor. Produces large clouds of vapor.
Shelf Life More chemically stable, resulting in a longer shelf life. More prone to oxidation and has a shorter shelf life.

Key Characteristics

  • Faster satisfaction: Nicotine is absorbed quickly, providing a rapid sense of satisfaction that helps curb cravings effectively, which is particularly beneficial for heavy smokers transitioning to vaping.
  • Ideal for new vapers: The smooth inhale and high nicotine content in small, easy-to-use devices (like pod systems) offer an experience closer to smoking a cigarette, making the switch easier.
  • Efficient and discreet: Users often need fewer puffs to be satisfied and produce less vapor, allowing for more discreet use and potentially less e-liquid consumption over time. 
  • Smoother experience: The reduced harshness allows users to comfortably vape higher nicotine concentrations without throat irritation.

Considerations 

  • Device limitations: Nicotine salts are generally not suitable for high-powered, sub-ohm devices, as this can lead to an overwhelming nicotine hit and potential negative side effects like nausea or dizziness.
  • Health risks: Like all nicotine products, salt nicotine is an addictive chemical and is not without health risks. It is not considered a "safe" alternative to smoking, but rather a less harmful option for current smokers looking to transition away from combustible tobacco. 
  • Higher potential for addiction: Due to the higher concentrations and smooth delivery, there is a potential for increased nicotine dependency.